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Dichloro­{4-chloro-2-[2-(diethyl­ammonio)­ethyl­iminometh­yl]phenolato-κ2N,O}copper(II)

✍ Scribed by Wang, Qing ;Qiu, Xiao-Yang

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
130 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [CuCl 2 (C 13 H 19 ClN 2 O)], is a mononuclear copper(II) complex. The Cu II ion is four-coordinated by the phenolate O and the imine N atoms of the Schiff base ligand, and by two Cl atoms, forming a distorted tetrahedral geometry.

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Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A R factor = 0.044 wR factor = 0.100 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the mononuclear copper(II) compound, [Cu(C 13 H 17 Cl 2 -N 2 O)(N 3 )], the Cu II ion is four-coordinated by one imine N, one amine N, and one phenolate O atom of the Schiff base ligand, and by one terminal N atom of an azide anion, forming a distorted square-planar coordination.