The title compound, [Cu(C 14 H 13 NO) 2 Cl 2 ], is a mononuclear copper(II) complex of a Schiff base. The Cu II atom is coordinated by two O atoms from two 2-(o-tolyliminomethyl)phenolate ligands, and by two chloride anions, forming a tetrahedral geometry.
Bis(2-{[5-fluoro-2-(trifluoromethyl)phenyl]iminomethyl}phenolato-κ2N,O)copper(II)
✍ Scribed by Wang, Liang-Gui ;Zheng, Yun-Fa
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 177 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [Cu(C 15 H 14 NO) 2 ], adopts a stepped conformation and displays a square-planar trans-[CuN 2 O 2 ] coordination geometry. The asymmetric unit contains two independent half molecules and each Cu atom is located on a center of symmetry. For one molecule, the CuÐN and CuÐO bond di
The crystal structure of the title complex, [Mn(C 9 H 9 NO 2 ) 2 ]Á-0.5H 2 O, contains two Mn IV units related by a twofold rotation axis and linked by intermolecular hydrogen bonds to a water molecule lying on this twofold axis.
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.008 A R factor = 0.061 wR factor = 0.212 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.