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Bis[1-(1-naphthyl­imino­meth­yl)-2-naphtholato-κ2N,O]copper(II)

✍ Scribed by Wang, Li ;Dong, Jian-Fang ;Li, Lian-Zhi ;Li, Lin-Wei ;Wang, Da-Qi

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
264 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 298 K Mean (C-C) = 0.008 A R factor = 0.061 wR factor = 0.212 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title complex, [Cu(C 17 H 12 NO) 2 ], the Cu II ion is coordinated by two bidentate ligands in a trans arrangement, forming a CuN 2 O 2 slightly distorted square-planar configuration.

Bis(2-acetyl-1-naphtholato-κ2O,O′)copper
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The asymmetric unit of the title compound, [Cu(C~12~H~9~O~2~)~2~], contains one half-molecule; the Cu atom lies on a centre of symmetry. The chelate ring is not planar and has a twist conformation. The dihedral angle between the naphthalene six-membered rings is 3.55 (3)°.