The asymmetric unit of the title compound, [Cu(C~12~H~9~O~2~)~2~], contains one half-molecule; the Cu atom lies on a centre of symmetry. The chelate ring is not planar and has a twist conformation. The dihedral angle between the naphthalene six-membered rings is 3.55 (3)°.
Aquabis(1-formyl-2-naphtholato-κ2O,O′)copper(II)
✍ Scribed by Yu, Qing ;Li, Chun-Ying ;Yang, Xiao-E ;He-Dong, Bian ;Liang, Hong
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 109 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.008 A R factor = 0.061 wR factor = 0.212 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Cu(C~8~H~6~NO~2~)~2~(C~6~H~7~NO)~2~(H~2~O)], the Cu^2+^ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of