In the title compound, [Cu(C~30~H~20~F~2~N~4~O~4~S~2~)]·0.5CH~2~Cl~2~, the Cu^II^ atom is four-coordinated by the N atoms of quinoline and sulfonamide groups in a distorted tetrahedral geometry. The solvent molecule lies on a twofold axis. Intermolecular C—H...O hydrogen bonds link the molecules int
Bis[N-(2-aminoethyl)-4-methylbenzenesulfonamidato]copper(II)
✍ Scribed by Hu, Man-Cheng ;Wei, Xiao-Yun ;Li, Shu-Ni
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 148 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Cu(C 9 H 13 N 2 O 2 S) 2 ], is a centrosymmetric neutral complex with the Cu II atom showing slightly distorted square-planar CuN 4 geometry. The crystal packing is consolidated by intramolecular N-HÁ Á ÁO and intermolecular C-HÁ Á Á interactions.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 299 K Mean (C-C) = 0.005 A R factor = 0.039 wR factor = 0.116 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, [Zn(C 24 H 29 N 2 O 2 S) 2 ], the Zn atom is four-coordinated by the N atoms of the sulfonamide and quinoline groups. The crystal packing is stabilized by intermolecular C-HÁ Á ÁO hydrogen bonds.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.045 wR factor = 0.095 Data-to-parameter ratio = 21.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.