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Bis[4-fluoro-N-(quinolin-8-yl)benzene­sulfonamidato-κ2N,N′]copper(II) dichloro­methane hemisolvate

✍ Scribed by Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
317 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cu(C~30~H~20~F~2~N~4~O~4~S~2~)]·0.5CH~2~Cl~2~, the Cu^II^ atom is four-coordinated by the N atoms of quinoline and sulfonamide groups in a distorted tetrahedral geometry. The solvent molecule lies on a twofold axis. Intermolecular C—H...O hydrogen bonds link the molecules into a three-dimensional network.

📜 SIMILAR VOLUMES

Bis[4-fluoro-N-(quinolin-8-yl)benzenesul
Bis[4-fluoro-N-(quinolin-8-yl)benzenesulfonamidato-κ2N,N′]zinc(II) hemihydrate
✍ Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 343 KB

In the title compound, [Zn(C~15~H~10~FN~2~O~2~ S)~2~]·0.5H~2~O, the Zn atom has a distorted tetrahedral geometry, formed by the N atoms of the quinoline and the sulfonamide groups. The water molecule occupies a special position on a twofold axis. Intermolecular C—H...O hydrogen bonds to the sulfonyl

Aqua­bis[4-nitro-N-(quinolin-8-yl)benzen
Aqua­bis[4-nitro-N-(quinolin-8-yl)benzene­sulfonamidato-κ2N,N′]zinc(II)
✍ Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 431 KB

Single-crystal X-ray study T = 299 K Mean (C-C) = 0.005 A R factor = 0.039 wR factor = 0.116 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis[2,4,6-triisopropyl-N-(quinolin-8-yl)
Bis[2,4,6-triisopropyl-N-(quinolin-8-yl)benzene­sulfonamidato-κ2N,N′]zinc(II)
✍ Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 320 KB

In the title compound, [Zn(C 24 H 29 N 2 O 2 S) 2 ], the Zn atom is four-coordinated by the N atoms of the sulfonamide and quinoline groups. The crystal packing is stabilized by intermolecular C-HÁ Á ÁO hydrogen bonds.

Bis[N-(5,7-dibromo­quinolin-8-yl)-3,5-bi
Bis[N-(5,7-dibromo­quinolin-8-yl)-3,5-bis­(trifluoro­meth­yl)benzene­sulfonamidato-κ2N,N′]zinc(II)
✍ Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 423 KB

In the title compound, [Zn(C 17 H 7 Br 2 F 6 N 2 O 2 S) 2 ], the zinc(II) ion has a distorted tetrahedral geometry formed by the N atoms of the quinoline and the sulfonamide groups. One intermolecular C-HÁ Á ÁO hydrogen bond to a sulfonyl O atom is observed.

Bis[N-(2-amino­ethyl)-4-methyl­benzene­s
Bis[N-(2-amino­ethyl)-4-methyl­benzene­sulfonamidato]copper(II)
✍ Hu, Man-Cheng ;Wei, Xiao-Yun ;Li, Shu-Ni 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 148 KB

The title compound, [Cu(C 9 H 13 N 2 O 2 S) 2 ], is a centrosymmetric neutral complex with the Cu II atom showing slightly distorted square-planar CuN 4 geometry. The crystal packing is consolidated by intramolecular N-HÁ Á ÁO and intermolecular C-HÁ Á Á interactions.