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Aqua­bis[4-nitro-N-(quinolin-8-yl)benzene­sulfonamidato-κ2N,N′]zinc(II)

✍ Scribed by Silva, Luiz Everson da ;Joussef, Antonio Carlos ;Foro, Sabine ;Schmidt, Boris

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
431 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 299 K Mean (C-C) = 0.005 A R factor = 0.039 wR factor = 0.116 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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In the title compound, [Cu(C~30~H~20~F~2~N~4~O~4~S~2~)]·0.5CH~2~Cl~2~, the Cu^II^ atom is four-coordinated by the N atoms of quinoline and sulfonamide groups in a distorted tetrahedral geometry. The solvent molecule lies on a twofold axis. Intermolecular C—H...O hydrogen bonds link the molecules int

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In the title compound, [Zn(C 17 H 7 Br 2 F 6 N 2 O 2 S) 2 ], the zinc(II) ion has a distorted tetrahedral geometry formed by the N atoms of the quinoline and the sulfonamide groups. One intermolecular C-HÁ Á ÁO hydrogen bond to a sulfonyl O atom is observed.

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Single-crystal X-ray study T = 299 K Mean (C-C) = 0.012 A R factor = 0.062 wR factor = 0.154 Data-to-parameter ratio = 12.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.