Bis[N-(2-aminoethyl)morpholine]copper(II) bis(tetrafluoroborate)
✍ Scribed by Sander, Ole ;Tuczek, Felix ;Näther, Christian
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 161 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Bis(1-chloromethyldiazabicyclo[2.2.2]octane-jN 4 )bis(trifluoropentane-2,4dionato)copper(II) bis(tetrafluoroborate)
The title compound, [Cu 2 (C 6 H 7 N 3 S 2 ) 2 (C 2 H 3 N) 2 ](BF 4 ) 2 , is a dimer with a central Cu 2 S 2 core resulting from thiosemicarbazone sulfur bridging. Both Cu-TCT units (TCT is the thiophene-2-carboxaldehyde thiosemicarbazone anion) are roughly planar and are parallel to one another and
The title compound, [Cu(C 9 H 13 N 2 O 2 S) 2 ], is a centrosymmetric neutral complex with the Cu II atom showing slightly distorted square-planar CuN 4 geometry. The crystal packing is consolidated by intramolecular N-HÁ Á ÁO and intermolecular C-HÁ Á Á interactions.