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Bis(di-2-pyridylmethane­diol-κ3N,N′,O)manganese(II) bis­(acetate) tetra­hydrate

✍ Scribed by Xie, Ming-Jin ;Lo, Kong Mun ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
186 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The Mn atom in the title compound, [Mn(C 11 H 10 N 2 O 2 ) 2 ]-(CH 3 CO 2 ) 2 Á4H 2 O, which lies on a centre of inversion, displays a tetragonally distorted octahedral coordination. The compound is isostructural with the analogous copper complex [Reinoso, Vitoria, San Felices, Lezama & Gutie ´rrez-Zorrilla (2003). Acta Cryst. E59, m548-m550].

📜 SIMILAR VOLUMES

Bis­(di-2-pyridyl­methanediol-κ3N,O,N′)c
Bis­(di-2-pyridyl­methanediol-κ3N,O,N′)copper(II) di­acetate tetrahydrate
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Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.049 wR factor = 0.115 Data-to-parameter ratio = 21.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Aqua­(3-carboxyl­atophenoxy­acetato-κO)bis­(1,10-phenanthroline-κ2N,N′)manganese(II) tetra­hydrate
✍ Gao, Shan ;Ng, Seik Weng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 194 KB

The dicarboxylate ligand in the title compound, [Mn(C 9 H 6 -O 5 )(C 12 H 8 N 2 ) 2 (H 2 O)]Á4H 2 O, coordinates in a monodentate manner to the Mn II atom through the carboxylate group on the benzene ring. The two O atoms in the octahedral configuration around the Mn II atom are cis to each other. E