Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.049 wR factor = 0.115 Data-to-parameter ratio = 21.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Bis(di-2-pyridylmethanediol-κ3N,O,N′)nickel(II) dilactate
✍ Scribed by Li, Cui-Jin ;Li, Wei ;Tong, Ming-Liang ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 247 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
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The Mn atom in the title compound, [Mn(C 11 H 10 N 2 O 2 ) 2 ]-(CH 3 CO 2 ) 2 Á4H 2 O, which lies on a centre of inversion, displays a tetragonally distorted octahedral coordination. The compound is isostructural with the analogous copper complex [Reinoso, Vitoria, San Felices, Lezama & Gutie ´rrez-
In mononuclear [Ni(C 8 H 11 N 2 O 3 S) 2 ], a nickel(II) complex of 2-(2-pyridylmethylamino)ethanesulfonic acid, the six-coordinate Ni atom lies on a centre of symmetry. The monodeprotonated anion coordinates in a facial arrangement through two N and one O atoms. Intermolecular N-HÁ Á ÁO hydrogen bo