✦ LIBER ✦

Bis[bis(diphenylphosphino)ethane]rhodium(I) tetraphenylborate

✍ Scribed by Bowen, Richard J. ;Coyanis, E. Mabel ;Layh, Marcus ;Meijboom, Reinout ;Poole, Craig B.

Publisher: International Union of Crystallography
Year: 2005
Tongue: English
Weight: 146 KB
Volume: 62
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536805040717

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, [Rh(C 26 H 24 ) 2 ](C 24 H 20 B), both the Rh and the B atom lie on twofold axes of symmetry. Selected geometrical parameters are Rh-P = 2.3076 (5) and 2.3114 (5) A ˚, and P-Rh-P = 82.43 (2) and 98.11 (2) .

📜 SIMILAR VOLUMES

Bis[μ-1,3-bis(diphenylphosphino)pro

Bis[μ-1,3-bis(diphenylphosphino)propane]disilver(I) bis(tetrafluoroborate)

✍ Smith, Michele L. ;Almond, Philip M. ;Albrecht-Schmitt, Thomas E. ;Hill, William 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 128 KB

[Bis(diphenylphosphino)ethane-P,P′)]

[Bis(diphenylphosphino)ethane-P,P′)][bis(diphenylphosphino)ethane sulfide-P)](thiobenzoato-S)copper(I)

✍ Deivaraj, Theivanayagam C. ;Vittal, Jagadese J. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 242 KB

The crystal structure of the title compound, [(dppe-P,P H )Cu-(dppeS-P)(SC{O}Ph)], [Cu(C 7 H 5 OS)(C 26 H 24 P 2 S)(C 26 H 24 P 2 )], is reported. In this monomeric compound, the Cu atom has a tetrahedral coordination geometry, with a P 3 CuS core.

Bis[1,2-bis(diphenylphosphino)ethan

Bis[1,2-bis(diphenylphosphino)ethane]silver(I) bis(trifluoroacetato)triphenylstannate(IV)

✍ Chee, Chin Fei ;Lo, Kong Mun ;Ng, Seik Weng 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 445 KB

Acta Cryst. (2003). E59, m273±m275 atoms at distances of ca 3.5 A Ê . The cations and anions exist as discrete entities in the unit cell (Fig. 3).

Bis(μ-Diphenylphosphino)ethane-κ2P:P′)-

Bis(μ-Diphenylphosphino)ethane-κ2P:P′)-bis[(O-ethyl N-phenylthiocarbamato-κS)gold(I)]

✍ Ho, Soo Yei ;Tiekink, Edward R. T. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 371 KB

(4,7-Diphenyl-1,10-phenanthroline)bis(t

(4,7-Diphenyl-1,10-phenanthroline)bis(triphenylphosphine)copper(I) tetrafluoroborate

✍ Che, Guang-Bo ;Li, Wen-Lian ;Li, Tian-Le ;Su, Zi-Sheng 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 159 KB

The title compound, [Cu(C 24 H 16 N 2 )(C 18 H 15 P) 2 ]BF 4 , consists of mononuclear Cu(PPh 3 ) 2 (NN) + and BF 4 À ions (NN is 4,7diphenyl-1,10-phenanthroline). The Cu I atom is four-coordinated by two P atoms of PPh 3 groups and two N donors of two NN ligands to form a tetrahedral coordination g

Bis[μ-bis(diphenylphosphino)methane-κ2

Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]bis[(1,10-phenanthroline-κ2N,N′)copper(I)] bis(tetrafluoroborate) dichloromethane disolvate

✍ Liu, Huan-Yu ;Wang, Fen-Ying ;Wang, Guo-Yong ;Huang, Chang-Gan ;Peng, Da-Yong 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 160 KB

Bis[l-bis(diphenylphosphino)methane-j 2 P:P 0 0 0 ]bis[(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(I)] bis(tetrafluoroborate) dichloromethane disolvate

Bis[bis­(diphenyl­phosphino)ethane]rhodium(I) tetra­phenyl­borate

✦ Synopsis

Bis[bis(diphenylphosphino)ethane]rhodium(I) tetraphenylborate