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[Bis(diphenylphosphino)ethane-P,P′)][bis(diphenylphosphino)ethane sulfide-P)](thiobenzoato-S)copper(I)

✍ Scribed by Deivaraj, Theivanayagam C. ;Vittal, Jagadese J.

Publisher: International Union of Crystallography
Year: 2002
Tongue: English
Weight: 242 KB
Volume: 58
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536802005810

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✦ Synopsis

The crystal structure of the title compound, [(dppe-P,P H )Cu-(dppeS-P)(SC{O}Ph)], [Cu(C 7 H 5 OS)(C 26 H 24 P 2 S)(C 26 H 24 P 2 )], is reported. In this monomeric compound, the Cu atom has a tetrahedral coordination geometry, with a P 3 CuS core.

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[Bis­(di­phenyl­phosphino)­ethane-P,P′)][bis­(di­phenyl­phosphino)­ethane sulfide-P)]­(thio­benzoato-S)copper(I)

✦ Synopsis

[Bis(diphenylphosphino)ethane-P,P′)][bis(diphenylphosphino)ethane sulfide-P)](thiobenzoato-S)copper(I)