In the title compound, [ZnCl~2~(C~14~H~23~N~5~)]·CH~3~OH, the Zn atom is coordinated by two N atoms and two Cl atoms in an approximately tetrahedral arrangement. The dihedral angle between the N—Zn—N and Cl—Zn—Cl planes is 89.69 (5)°. The methanol solvent molecule takes part in the formation of the
[Bis(2-pyridylmethyl)amine]dichloridozinc(II) chloroform solvate
✍ Scribed by Kim, Young-Inn ;Lee, You-Soon ;Seo, Hoe-Joo ;Lee, Jin-Young ;Kang, Sung Kwon
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 349 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The Zn atom in the title complex, [ZnCl~2~(C~12~H~13~N~3~)]·CHCl~3~, adopts a distorted square-pyramidal geometry, being coordinated by three N atoms of the tridentate dipicolylamine ligand and two Cl atoms. Intermolecular N—H...Cl hydrogen-bonding interactions link the molecules into centrosymmetric dimers.
📜 SIMILAR VOLUMES
In the title compound, [Ru(C 4 H 3 N 2 S) 2 (C 18 H 15 P) 2 ]ÁCHCl 3 , the Ru atom has a distorted octahedral environment formed by two S and two N atoms from the pyrimidine-2-thiolate ligands and two P atoms from the triphenylphosphine ligands. Intramolecularinteractions between the pyrimidine and