The Zn atom in the title complex, [ZnCl~2~(C~12~H~13~N~3~)]·CHCl~3~, adopts a distorted square-pyramidal geometry, being coordinated by three N atoms of the tridentate dipicolylamine ligand and two Cl atoms. Intermolecular N—H...Cl hydrogen-bonding interactions link the molecules into centrosymmetri
Bis(2-pyridylmethyl)amine–borane
✍ Scribed by Sanchez Ballester, Noelia ;Barreira Fontecha, Julia ;Wikaira, Jan ;McKee, Vickie
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 189 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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Single-crystal X-ray study T = 113 K Mean '(C±C) = 0.005 A Ê R factor = 0.056 wR factor = 0.163 Data-to-parameter ratio = 15.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, __fac__-[InBr~3~{NH(CH~2~C~5~H~4~N)~2~}], the In^III^ atom is coordinated by three bromide ligands and a tridentate bis(2-pyridylmethyl)amine ligand. A mirror plane passes through the In atom, one Br atom and central NH group. The molecule exhibits facial octahedral stereochem
The dinuclear Fe^III^ complex in the title compound, [Fe~2~Cl~2~O(C~18~H~18~N~4~)~2~](PF~6~)~2~, lies on a center of inversion. The Fe^III^ atom is chelated by a tetradentate tris(2-pyridylmethyl)amine ligand __via__ four N atoms and further coordinated by one chloride ion and one bridging oxide O a
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.055 wR factor = 0.156 Data-to-parameter ratio = 9.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The crystal structure of the title compound, 2,6-bis[bis(2pyridyl)hydroxymethyl]pyridine, C 27 H 21 N 5 O 2 , at 180 K contains intramolecular OÐHÁ Á ÁN contacts. In space group C2/c, the molecule is sited on a twofold axis.