𝔖 Bobbio Scriptorium
✦   LIBER   ✦

μ-Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]iron(III)} bis(hexafluoridophosphate)

✍ Scribed by Liu, Ying ;Dou, Jianmin ;Li, Dacheng ;Zhang, Xianxi

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
440 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The dinuclear Fe^III^ complex in the title compound, Fe~2~Cl~2~O(C~18~H~18~N~4~)~2~~2~, lies on a center of inversion. The Fe^III^ atom is chelated by a tetradentate tris(2-pyridylmethyl)amine ligand via four N atoms and further coordinated by one chloride ion and one bridging oxide O atom, giving a distorted octahedral coordination geometry.

📜 SIMILAR VOLUMES

Azido­[bis(2-oxido­phenyl­methyl­ene­imi
Azido­[bis(2-oxido­phenyl­methyl­ene­imino)­propane-1,2-di­amine(2–)]­iron(III)
✍ Liu, Zhao-Di ;Tan, Min-Yu ;Zhu, Hai-Liang 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 338 KB

Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.008 A Ê Disorder in main residue R factor = 0.072 wR factor = 0.225 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

μ-Oxo-bis{chloro­[N,N′-di­methyl-N,N′-bi
μ-Oxo-bis{chloro­[N,N′-di­methyl-N,N′-bis(2-pyridyl­methyl)­ethane-1,2-di­amine]iron(III)} diperchlorate 0.751-hydrate
✍ Egdal, Rune Kirk ;Hazell, Alan ;McKenzie, Christine J. 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 345 KB

Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.003 A Ê Disorder in solvent or counterion R factor = 0.032 wR factor = 0.034 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.