The title vanadium complex, [VClO(C 16 H 22 N 4 )]ClO 4 , of the tetradentate ligand N,N H -dimethyl-N,N H -bis(2-pyridylmethyl)ethane-1,2-diamine was obtained from air oxidation of a mixture of the ligand and VCl 3 in wet methanol.
μ-Oxo-bis{chloro[N,N′-dimethyl-N,N′-bis(2-pyridylmethyl)ethane-1,2-diamine]iron(III)} diperchlorate 0.751-hydrate
✍ Scribed by Egdal, Rune Kirk ;Hazell, Alan ;McKenzie, Christine J.
- Publisher
- International Union of Crystallography
- Year
- 2001
- Tongue
- English
- Weight
- 345 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.003 A Ê Disorder in solvent or counterion R factor = 0.032 wR factor = 0.034 Data-to-parameter ratio = 16.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.009 A Ê R factor = 0.057 wR factor = 0.136 Data-to-parameter ratio = 19.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title compound, (C 5 H 14 N 2 ) 2 [Bi 2 Cl 10 ]Á2H 2 O, each Bi III atom of the centrosymmetric anion is six-coordinate in a distorted octahedral geometry. The salt adopts a threedimensional network arising from the hydrogen bonds between the cations, anions and water molecules.