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fac-[Bis(2-pyridylmeth­yl)amine-κ3N]tribromo­indium(III)

✍ Scribed by Itazaki, Masumi ;Ujihara, Rie ;Nakazawa, Hiroshi

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
103 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, fac-[InBr~3~{NH(CH~2~C~5~H~4~N)~2~}], the In^III^ atom is coordinated by three bromide ligands and a tridentate bis(2-pyridylmethyl)amine ligand. A mirror plane passes through the In atom, one Br atom and central NH group. The molecule exhibits facial octahedral stereochemistry, with In—Br bond lengths of 2.5682 (13) and 2.6060 (9) Å, and In—N bond lengths of 2.311 (6) and 2.328 (9) Å.

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