Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.007 A Ê R factor = 0.049 wR factor = 0.069 Data-to-parameter ratio = 20.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Bis(pyrimidine-2-thiolato)bis(triphenylphosphine)ruthenium(II) chloroform solvate
✍ Scribed by Li, Zhengkai ;Zhao, Jin ;Liang, Lei ;Zhou, Xiangge
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 351 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Ru(C 4 H 3 N 2 S) 2 (C 18 H 15 P) 2 ]ÁCHCl 3 , the Ru atom has a distorted octahedral environment formed by two S and two N atoms from the pyrimidine-2-thiolate ligands and two P atoms from the triphenylphosphine ligands. Intramolecularinteractions between the pyrimidine and phenyl rings of triphenylphosphine are observed.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.008 A Ê R factor = 0.038 wR factor = 0.090 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The crystal structure of [RuCl 2 (C 13 H 13 N 3 ) 2 ] contains complexes on general positions and complexes located on crystallographic twofold rotation axes. The three independent 2-phenylazo-4,6-dimethylpyridine ligands all have the same conformation.