𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis­(pyrimidine-2-thiol­ato)­bis­(tri­phenyl­phosphine)­ruthenium(II) chloro­form solvate

✍ Scribed by Li, Zhengkai ;Zhao, Jin ;Liang, Lei ;Zhou, Xiangge


Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
351 KB
Volume
61
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


In the title compound, [Ru(C 4 H 3 N 2 S) 2 (C 18 H 15 P) 2 ]ÁCHCl 3 , the Ru atom has a distorted octahedral environment formed by two S and two N atoms from the pyrimidine-2-thiolate ligands and two P atoms from the triphenylphosphine ligands. Intramolecularinteractions between the pyrimidine and phenyl rings of triphenylphosphine are observed.


📜 SIMILAR VOLUMES


syn-Tetra­carbonyl­di-μ-phenyl­thiol­ato
✍ Shiu, Kom-Bei ;Liao, Fen-Ling ;Wang, Sue-Lein 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 261 KB

Single-crystal X-ray study T = 294 K Mean '(C±C) = 0.007 A Ê R factor = 0.049 wR factor = 0.069 Data-to-parameter ratio = 20.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Di­bromo­di­carbonyl­bis­(tri­phenyl­pho
✍ Lozano Diz, Enrique ;Therrien, Bruno ;Neels, Antonia ;Süss-Fink, Georg 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 193 KB

Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.008 A Ê R factor = 0.038 wR factor = 0.090 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

α-Di­chloro­bis(2-phenyl­azo-4,6-di­meth
✍ Kooijman, Huub ;Hotze, Anna C. G. ;Caspers, Sabrine E. ;Haasnoot, Jaap G. ;Reedi 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 476 KB

The crystal structure of [RuCl 2 (C 13 H 13 N 3 ) 2 ] contains complexes on general positions and complexes located on crystallographic twofold rotation axes. The three independent 2-phenylazo-4,6-dimethylpyridine ligands all have the same conformation.