In the title compound, [Ni(C~7~H~19~N~3~O)~2~](ClO~4~)~2~, the Ni atom, which is located on an inversion center, is hexacoordinated by six N atoms from two ligands, forming a distorted octahedron. The complex molecules are linked by N—H...O hydrogen bonding, forming a one-dimensional chain structure
Bis{2-[N,N-bis(2-aminoethyl)amino]ethanaminium}nickel(II) hexacyanidoferrate(II)
✍ Scribed by Yao, Yue-Juan ;Shu, Hui-Ming ;Du, Chuan-Qin ;Hu, Huai-Ming
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 306 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Ni(C 6 H 19 N 4 ) 2 ][Fe(CN) 6 ], the Ni 2+ and Fe 2+ cations are both octahedrally coordinated. The complex cations and anions, both of which are centrosymmetric, are linked by a network of N-HÁ Á ÁN hydrogen bonds to form a three-dimensional network.
metal-organic papers m1210 Yao et al. [Ni(C 6 H 19 N 4 ) 2 ][Fe(CN) 6 ]
📜 SIMILAR VOLUMES
The title compound, [Cu(C 9 H 13 N 2 O 2 S) 2 ], is a centrosymmetric neutral complex with the Cu II atom showing slightly distorted square-planar CuN 4 geometry. The crystal packing is consolidated by intramolecular N-HÁ Á ÁO and intermolecular C-HÁ Á Á interactions.
Diaminopropane-j 2 N,N 0 0 0 )[tris(2-aminoethyl)amine-j 4 N,N 0 0 0 ,N 0 0 00 0 0 ,N 0 0 00 0 00 0 0 ]nickel(II) bis(perchlorate)