𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis{2-[N,N-bis(2-aminoethyl)amino]ethanaminium}nickel(II) hexacyanidoferrate(II)

✍ Scribed by Yao, Yue-Juan ;Shu, Hui-Ming ;Du, Chuan-Qin ;Hu, Huai-Ming


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
306 KB
Volume
63
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis


In the title compound, [Ni(C 6 H 19 N 4 ) 2 ][Fe(CN) 6 ], the Ni 2+ and Fe 2+ cations are both octahedrally coordinated. The complex cations and anions, both of which are centrosymmetric, are linked by a network of N-HÁ Á ÁN hydrogen bonds to form a three-dimensional network.

metal-organic papers m1210 Yao et al. [Ni(C 6 H 19 N 4 ) 2 ][Fe(CN) 6 ]


📜 SIMILAR VOLUMES


Bis{1-[bis(2-aminoethyl)amino]propan-2-o
✍ Qian, Bao-Hua ;Zhang, Zhen-Ming ;Lu, Lu-De ;Yang, Xu-Jie ;Wang, Xin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 519 KB

In the title compound, [Ni(C~7~H~19~N~3~O)~2~](ClO~4~)~2~, the Ni atom, which is located on an inversion center, is hexacoordinated by six N atoms from two ligands, forming a distorted octahedron. The complex molecules are linked by N—H...O hydrogen bonding, forming a one-dimensional chain structure

Bis[N-(2-amino­ethyl)-4-methyl­benzene­s
✍ Hu, Man-Cheng ;Wei, Xiao-Yun ;Li, Shu-Ni 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 148 KB

The title compound, [Cu(C 9 H 13 N 2 O 2 S) 2 ], is a centrosymmetric neutral complex with the Cu II atom showing slightly distorted square-planar CuN 4 geometry. The crystal packing is consolidated by intramolecular N-HÁ Á ÁO and intermolecular C-HÁ Á Á interactions.