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Bis{1-[bis(2-aminoethyl)amino]propan-2-ol}nickel(II) bis(perchlorate)

✍ Scribed by Qian, Bao-Hua ;Zhang, Zhen-Ming ;Lu, Lu-De ;Yang, Xu-Jie ;Wang, Xin

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
519 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, Ni(C~7~H~19~N~3~O)~2~~2~, the Ni atom, which is located on an inversion center, is hexacoordinated by six N atoms from two ligands, forming a distorted octahedron. The complex molecules are linked by N—H...O hydrogen bonding, forming a one-dimensional chain structure along the a axis, which is further hydrogen bonded with the perchlorate anion to form a three-dimensional framework. One —CH~2~—CH~2~— group is disordered over two positions; the site occupancy factors are ca. 0.6 and 0.4.

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