Orthophosphate Binding to Zinc(II) Complexes of 1,3-Bis[Bis(Pyridin-2-Ylmethyl)Amino] Propan-2-Ol
✍ Scribed by Liberato Ciavatta; Francesco Salvatore
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 258 KB
- Volume
- 97
- Category
- Article
- ISSN
- 0003-4592
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.011 A Disorder in solvent or counterion R factor = 0.054 wR factor = 0.098 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
## Abstract The stability constants of the Cu^II^ chelates with the tripodal heptadentate ligand tris{2‐[(2‐pyridylmethyl)amino]ethyl}amine (=__N__′‐(pyridin‐2‐ylmethyl)‐__N,N__‐bis{2‐[(pyridin‐2‐ylmethyl)amino]ethyl}ethane‐1,2‐diamine; tpaa), determined by potentiometry and UV spectrometry, show t
The Zn II atom in the title complex, [Zn(C 11 H 13 N 2 O 6 ) 2 ]Á-C 5 H 5 N, is chelated by a terdentate Schiff base ligand in a slightly distorted octahedral geometry. One of the coordinated hydroxyl groups forms a hydrogen bond with the pyridine solvent molecule. In the crystal structure, other hy