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Bis[1,3-dihydr­oxy-2-hydroxy­methyl-2-(5-nitro-2-oxidobenzylideneamino)propane-κ3N,O,O′]zinc(II) pyridine solvate

✍ Scribed by Ali, Hapipah M. ;Puvaneswary, Subramaniam ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
148 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

The Zn II atom in the title complex, [Zn(C 11 H 13 N 2 O 6 ) 2 ]Á-C 5 H 5 N, is chelated by a terdentate Schiff base ligand in a slightly distorted octahedral geometry. One of the coordinated hydroxyl groups forms a hydrogen bond with the pyridine solvent molecule. In the crystal structure, other hydroxyl groups are engaged in intermolecular hydrogen bonding, forming a two-dimensional layer.

📜 SIMILAR VOLUMES

Bis[1,3-dihydroxy-2-hydroxymethyl-2-(5-n
Bis[1,3-dihydroxy-2-hydroxymethyl-2-(5-nitro-2-oxidobenzylideneamino)propane-κ3N,O,O′]zinc(II) trihydrate
✍ Ali, Hapipah M. ;Puvaneswary, Subramaniam ;Wan Jefrey, Basirun ;Ng, Seik Weng 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 788 KB

The Zn atom in the title compound, [Zn(C 11 H 13 N 2 O 6 ) 2 ]Á3H 2 O, is chelated by the two terdentate Schiff base anions, resulting in a trans-ZnN 2 O 4 octahedral geometry. The crystal packing is stabilized by O-HÁ Á ÁO hydrogen bonds, leading to a threedimensional network structure. ## Related