[Bis(2-methyl-1-pyridyl)phenylphosphine-κ2N,P,N′]trichlorochromium(III) acetonitrile solvate
✍ Scribed by Klausmeyer, Kevin K. ;Hung, Fernando
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 116 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title complex, [PdCl 2 (C 16 H 18 N 2 )]ÁC 2 H 3 N, contains a slightly distorted square planar Pd II center coordinated by two N and two Cl atoms. The crystal packing is stabilized by C-HÁ Á ÁCl interactions.
{l-Bis [1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-j 2 N,N 0 0 0 }bis[iodo(triphenylphosphine-jP)copper(I)] acetonitrile disolvate
The title compound, [Pt(N~2~S~2~)(C~13~H~13~P)~2~]·CH~2~Cl~2~, contains Pt^II^ in a square-planar coordination. The five-membered PtS~2~N~2~ ring contains two short and one long S—N bonds. Interestingly, the S—N bond lengths have a different pattern from those in the PMe~2~Ph analogue and one of the
The title compound, [Pd(C 2 H 3 O 2 )(C 18 H 15 P)(C 12 H 11 N 2 O)]Á-CH 2 Cl 2 , crystallizes readily from a mixture of dichloromethane and light petroleum. The structure is one of few examples of palladacycles that incorporate the N-substituent in five-membered-ring heterocycles [Nonoyama & Nakaji
The asymmetric unit of the title compound, [FePd-(C 5 H 5 )(C 11 H 15 NO)Cl(C 18 H 15 P)]ÁCH 2 Cl 2 , contains two molecular palladium complexes and two dichloromethane solvent molecules. The Pd atoms have approximately square planar configurations. Intermolecular O-HÁ Á ÁCl hydrogen bonds stabilize