The tridentate Schiff base ligand derived from the condensation of salicylaldehyde and dl-tyrosine, in the presence of pyridine, forms a square-pyramidal ®ve-coordinate Cu complex, [Cu(C 16 H 13 NO 4 )(C 5 H 5 N)(H 2 O)], with a water molecule occupying the apical site.
Aqua(pyridine-κN)(N-salicylideneglycinato-κ3N,O,O′)copper(II)
✍ Scribed by Li, Yu-Guang ;Zhu, Hai-Liang ;Chen, Xin-Zhi ;Ng, Seik Weng
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 267 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [Cu(C~8~H~6~NO~2~)~2~(C~6~H~7~NO)~2~(H~2~O)], the Cu^2+^ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of
Aqua(2,2 0 0 0 -bipyridine-j 2 N,N 0 0 0 )(L-malato-j 3 O,O 0 0 0 ,O 0 0 00 0 0 )copper(II)
In the title complex, [Cu(C~8~H~5~O~3~)(NO~3~)(C~12~H~8~N~2~)(H~2~O)], the Cu^II^ atom adopts a distorted square-pyramidal coordination geometry with an O atom of the nitrate group occupying the apex of the pyramid. The complex molecules are linked into ribbons along the __a__ axis __via__ hydrogen