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Aqua[N,N′-bis(4-methyl-1,3-benzothiazol-2-yl)pyridine-2,6-dicarboxamidato(2−)]copper(II)

✍ Scribed by Liu, Sheng-Gui ;Ni, Chun-Lin ;Li, Yi-Zhi

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 159 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807014365

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✦ Synopsis

Treatment of deprotonated N,N 0 -bis-(4-methyl-2-benzothiazolyl)-2,6-pyridicarboxamide (L 2À ) with CuCl 2 Á2H 2 O yields the mononuclear title complex, CuL(H 2 O) or [Cu(C 23 H 15 N 5 -O 2 S 2 )(H 2 O)]. The Cu II atom adopts a distorted square-planar coordination geometry, binding to two deprotonated amide N atoms, the pyridine N atom and the water O atom. In the crystal structure, weak C-HÁ Á ÁO and C-HÁ Á ÁS hydrogen bonds, and C-HÁ Á Á andinteractions stabilize the crystal structure.

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