{N,N′-Bis[2-(methylsulfanyl)phenyl]pyridine-2,6-dicarboxamidato(2–)}nickel(II)
✍ Scribed by Liu, Sheng-Gui ;Li, Yi-Zhi ;Zuo, Jing-Lin ;You, Xiao-Zeng
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 479 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Bis(tetraethylammonium) bis[N,N 0 0 0 -bis(4-methylbenzothiazol-2-yl)pyridine-2,6-dicarboxamidato(2-)]nickel(II) hemihydrate
Treatment of deprotonated N,N 0 -bis-(4-methyl-2-benzothiazolyl)-2,6-pyridicarboxamide (L 2À ) with CuCl 2 Á2H 2 O yields the mononuclear title complex, CuL(H 2 O) or [Cu(C 23 H 15 N 5 -O 2 S 2 )(H 2 O)]. The Cu II atom adopts a distorted square-planar coordination geometry, binding to two deprotona
In the title compound, [Ni(C 16 H 16 N 3 O 2 ) 2 ]ÁC 2 H 6 OS, the Ni II atom lies on a crystallographic centre of symmetry and its coordination geometry is distorted square-planar, involving four N atoms from two oxime ligands. The dimethyl sulfoxide solvent is disordered over a crystallographic tw