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Bis­[N-(2,6-di­methyl­phenyl)­amino­phenyl­glyoximato-κ2N,N′]­nickel(II) di­methyl sulfoxide solvate

✍ Scribed by Batı, Hümeyra ;Zülfikaroğlu, Ayşin ;Taş, Murat ;Çalışkan, Nezihe ;Soylu, Serkan ;Andac, Omer ;Büyükgüngör, Orhan


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
213 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Ni(C 16 H 16 N 3 O 2 ) 2 ]ÁC 2 H 6 OS, the Ni II atom lies on a crystallographic centre of symmetry and its coordination geometry is distorted square-planar, involving four N atoms from two oxime ligands. The dimethyl sulfoxide solvent is disordered over a crystallographic twofold axis.


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Redetermination of bis­(di­methyl­glyoxi
✍ Li, Dai-Xi ;Xu, Duan-Jun ;Xu, Yuan-Zhi 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 280 KB

Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.005 A Ê R factor = 0.034 wR factor = 0.103 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.