Aqua(4′-hydroxy-2,2′;6′,6′′-terpyridyl)copper(II) bis(perchlorate)
✍ Scribed by Jeitler, James R. ;Turnbull, Mark M.
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 170 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Aqua(4 0 0 0 -hydroxy-2,2 0 0 0 ;6 0 0 0 ,6 0 0 00 0 0 -terpyridyl)copper(II) bis(perchlorate)
📜 SIMILAR VOLUMES
In the title compound, C 22 H 24 ClNO 5 , the carbonyl group is in an s-cis configuration with respect to the olefinic double bond. In the crystal structure, there are weak -stacking interactions but there are no significant intermolecular hydrogen bonds.
The Cu^II^ ion of the title complex, [Cu(SO~4~)(C~15~H~11~N~3~O)(H~2~O)]·2H~2~O, exhibits a square-pyramidal coordination geometry, defined by the three N-atom donors of a 2,6-bis(pyridin-2-yl)pyridin-4-ol ligand and an O atom of a sulfate group in the basal plane, and by an aqua ligand in the apica
Treatment of deprotonated N,N 0 -bis-(4-methyl-2-benzothiazolyl)-2,6-pyridicarboxamide (L 2À ) with CuCl 2 Á2H 2 O yields the mononuclear title complex, CuL(H 2 O) or [Cu(C 23 H 15 N 5 -O 2 S 2 )(H 2 O)]. The Cu II atom adopts a distorted square-planar coordination geometry, binding to two deprotona
The title compound, C 19 H 18 N 4 O 8 , belonging to the pyrimidinyloxybenzoic acid family, exhibits herbicidal properties. The crystal structure is stabilized by C-HÁ Á ÁO and O-HÁ Á ÁN intermolecular hydrogen bonds.
Bis[l-4,4 0 0 0 -methylenebis(3-hydroxy-2-naphthoatoj 2 O:O 0 0 0 )]bis[aqua(ethylenediamine-j 2 N,N 0 0 0 )copper(II)]