Aqua(2,2′-bipyridine)(2,2′:6′,2′′-terpyridine)ruthenium(II) bis(perchlorate)
✍ Scribed by Qvortrup, Katrine ;McKenzie, Christine J. ;Bond, Andrew D.
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 189 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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Acetylacetonato)aqua(2,2 0 0 0 ,2 0 0 00 0 0 -terpyridine)chromium(III) bis(perchlorate) dihydrate hexamethylphosphoramide solvate
## Abstract A new series of dendrimers was assembled through formation of homo‐ and heteroleptic Ru^II^ complexes with [2,2′: 6′,2″]terpyridine ligands bearing hydrophilic and hydrophobic dendrons, with the aim to develop amphiphilic vectors for potential use in gene delivery (__Scheme 1__). The sy
The title compound, [Co~2~(HO~3~PCH~2~CH~2~COO)~2~(C~10~H~8~N~2~)~2~(H~2~O)~2~], was obtained by a hydrothermal method. Two six-coordinate cobalt(II) ions are linked by two 2-carboxyethylphosphonate ligands, forming a centrosymmetric dimer. The dimers are further interlinked by O—H...O hydrogen bond
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê Disorder in solvent or counterion R factor = 0.049 wR factor = 0.151 Data-to-parameter ratio = 14.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.