The title dinuclear Co II complex, [Co 2 (C 8 H 7 O 2 ) 4 (C 12 H 8 N 2 ) 2 -(H 2 O)], has C 2 symmetry with the coordinated water O atom located on a twofold axis. Two Co II ions are bridged by two methylbenzoate (MBZ) anions and one water molecule. Each Co II ion displays a distorted octahedral co
Bis[μ-4,4′-methylenebis(3-hydroxy-2-naphthoato-κ2O:O′)]bis[aqua(ethylenediamine-κ2N,N′)copper(II)]
✍ Scribed by Yin, Wei-Rong ;Ye, Jun-Wei ;Ye, Ling ;Zhang, Ping ;Xu, Jia-Ning
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 549 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Bis[l-4,4 0 0 0 -methylenebis(3-hydroxy-2-naphthoatoj 2 O:O 0 0 0 )]bis[aqua(ethylenediamine-j 2 N,N 0 0 0 )copper(II)]
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.089 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Cu(C~8~H~6~NO~2~)~2~(C~6~H~7~NO)~2~(H~2~O)], the Cu^2+^ ion has a highly distorted square-bipyramidal (4 + 1 + 1) coordination environment, and is bonded to three carboxylate O atoms of two 3-pyridylacrylate anions (monodentate and asymetric bidentate), two pyridine N atoms of