In the title compound, [Cu(C 15 H 11 N 2 O 2 ) 2 (C 3 H 4 N 2 ) 2 ]ÁH 2 O, the Cu II ion has a distorted square-planar CuN 4 coordination environment. The crystal structure is stabilized by intermolecular hydrogen bonding.
Aqua[1,3-propanediyldiiminobis(1,3-dimethyl-5-nitrosouracilato)-κ4N5,N6,N15,N16]copper(II) Monohydrate
✍ Scribed by Kivekäs, R. ;Klinga, M. ;Colacio, E. ;Dominguez-Vera, J. M. ;Romerosa, A.
- Book ID
- 114511759
- Publisher
- International Union of Crystallography
- Year
- 1995
- Tongue
- English
- Weight
- 337 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0108-2701
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The title compound, [CuCl 2 (C 12 was obtained by the reaction of 1,10-phenanthroline-5,6-dione (phendione) and CuCl 2 Á2H 2 O. The copper(II) ion is pentacoordinated in a distorted squarepyramidal environment. The water molecule connects the complex and a dimethyl sulfoxide solvent molecule by O-H
Single-crystal X-ray study T = 120 K Mean (C-C) = 0.009 A Some non-H atoms missing R factor = 0.066 wR factor = 0.176 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.