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Bis(5,5-diphenyl­hydantoinato-κN3)bis­(1H-imidazole-κN3)copper(II) monohydrate

✍ Scribed by Xu, Xing-You ;Xu, Tong-Tao ;Ma, He-Ping ;Hu, Xi-Lan ;Wang, Da-Qi

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
131 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [Cu(C 15 H 11 N 2 O 2 ) 2 (C 3 H 4 N 2 ) 2 ]ÁH 2 O, the Cu II ion has a distorted square-planar CuN 4 coordination environment. The crystal structure is stabilized by intermolecular hydrogen bonding.

📜 SIMILAR VOLUMES

trans-Bis(5,5-diphenyl­hydantoinato-κN3)
trans-Bis(5,5-diphenyl­hydantoinato-κN3)bis­(furfurylamine-κN)copper(II) 5,5-diphenyl­hydantoin disolvate
✍ Hu, Xi-Lan ;Xu, Xing-You ;Xu, Tong-Tao ;Wang, Da-Qi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 247 KB

In the title compound, [Cu(C 15 H 11 N 2 O 2 ) 2 (C 5 H 7 NO) 2 ]-(C 15 H 12 N 2 O 2 ) 2 , the Cu II ion, lying on an inversion centre, is coordinated in a square-planar coordination geometry; two other 5,5-diphenylhydantoin molecules are uncoordinated. The crystal structure includes intermolecular

trans-Diaqua­bis(5,5-diphenyl­hydantoina
trans-Diaqua­bis(5,5-diphenyl­hydantoinato-κN3)copper(II)
✍ Hu, Xi-Lan ;Xu, Xing-You ;Wang, Da-Qi ;Xu, Tong-Tao 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 144 KB

The molecule of the title complex, [Cu(C 15 H 11 N 2 O 2 ) 2 (H 2 O) 2 ], lies on a twofold rotation axis. The crystal structure is based on a network of intermolecular N-HÁ Á ÁO C and O-HÁ Á ÁO C interactions.

Bis(1H-imidazole-κN3)­bis(3-methyl­benzo
Bis(1H-imidazole-κN3)­bis(3-methyl­benzoato-κO)copper(II)
✍ Xu, Tu-Gen ;Liu, Jia-Geng ;Xu, Duan-Jun 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 301 KB

In the title complex, [Cu(C 8 H 7 O 2 ) 2 (C 3 H 4 N 2 ) 2 ], the Cu II atom, located on an inversion center, has a square-planar coordination geometry formed by imidazole molecules and 3methylbenzoate anions. Hydrogen-bonding and C-HÁ Á Á interactions occur between imidazole and methylbenzoate liga