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Aqua­[()-lactate-O,O′](1,10-phenanthroline-κ2N,N′)copper(II) nitrate

✍ Scribed by Medina, Gerardo ;Gasque, Laura ;Bernès, Sylvain


Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
310 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the structure of the title compound, [Cu(C 3 H 5 O 3 )-(C 12 H 8 N 2 )(H 2 O)]NO 3 , the Cu II ion is ®ve-coordinated through two N atoms of the 1,10-phenanthroline ligand, two O atoms of the lactate anion and a water molecule. The cations are well separated in the unit cell, the shortest metal±metal separation being 6.2127 (8) A Ê .


📜 SIMILAR VOLUMES


Aqua(4-formylbenzoato-κO)(nitrato-κO)(1,
✍ Deng, Zhao-Peng ;Gao, Shan ;Huo, Li-Hua ;Zhao, Hui 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 534 KB

In the title complex, [Cu(C~8~H~5~O~3~)(NO~3~)(C~12~H~8~N~2~)(H~2~O)], the Cu^II^ atom adopts a distorted square-pyramidal coordination geometry with an O atom of the nitrate group occupying the apex of the pyramid. The complex molecules are linked into ribbons along the __a__ axis __via__ hydrogen

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✍ Harrison, William T. A. ;Ramadevi, Palani ;Kumaresan, Sudalaiandi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 472 KB

The title compound, [Zn(C 7 H 3 NO 4 )(C 12 H 8 N 2 )(H 2 O)]ÁH 2 O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO 3 N 3 octa