l 2 -Oxalato-j 2 O,O 0 0 0 :j 2 O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 -bis[aqua(1,10-phenanthroline-j 2 N,N 0 0 0 )copper(II)] dinitrate dihydrate
Aqua[()-lactate-O,O′](1,10-phenanthroline-κ2N,N′)copper(II) nitrate
✍ Scribed by Medina, Gerardo ;Gasque, Laura ;Bernès, Sylvain
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 310 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the structure of the title compound, [Cu(C 3 H 5 O 3 )-(C 12 H 8 N 2 )(H 2 O)]NO 3 , the Cu II ion is ®ve-coordinated through two N atoms of the 1,10-phenanthroline ligand, two O atoms of the lactate anion and a water molecule. The cations are well separated in the unit cell, the shortest metal±metal separation being 6.2127 (8) A Ê .
📜 SIMILAR VOLUMES
In the title complex, [Cu(C~8~H~5~O~3~)(NO~3~)(C~12~H~8~N~2~)(H~2~O)], the Cu^II^ atom adopts a distorted square-pyramidal coordination geometry with an O atom of the nitrate group occupying the apex of the pyramid. The complex molecules are linked into ribbons along the __a__ axis __via__ hydrogen
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h
The title compound, [Zn(C 7 H 3 NO 4 )(C 12 H 8 N 2 )(H 2 O)]ÁH 2 O, is isostructural with the manganese(II) analogue. The Zn atom is coordinated by a tridentate dipicolinate dianion, a bidentate 1,10-phenanthroline molecule and a water molecule, resulting in a substantially distorted ZnO 3 N 3 octa