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Allylsilanes in organic synthesis; stereoselective synthesis of trans-alkene peptide isosteres

โœ Scribed by Matthew J. Daly; Richard A. Ward; David F. Thompson; Garry Procter

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
247 KB
Volume
36
Category
Article
ISSN
0040-4039

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A stereocontrolled synthesis of trans-al
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Allylsilanes in organic synthesis; stere
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The ester-allylsilanes ( 5) and ( 6) and the acid-allylsilane (7) react stereoselectively with m-CPBA; the major product from ( 5) and ( 7) was the y-lactone (4), whereas (6) failed to undergo lactonisation, the major product in this case was the P,wpoxy-silane (12).