Allylsilanes in organic synthesis; stereoselective reaction of chiral ester-allylsilanes with m-CPBA

✍ Scribed by Andrew T. Russell; Garry Procter

• Publisher: Elsevier Science
• Year: 1987
• Tongue: French
• Weight: 229 KB
• Volume: 28
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)96041-6

✦ Synopsis

The ester-allylsilanes ( 5) and ( 6) and the acid-allylsilane (7) react stereoselectively with m-CPBA; the major product from ( 5) and ( 7) was the y-lactone (4), whereas (6) failed to undergo lactonisation, the major product in this case was the P,wpoxy-silane (12).