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Allylsilanes in organic synthesis; Stereoselective hydroxylactonisation of chiral amide-allylsilanes

โœ Scribed by Andrew T. Russell; Garry Procter

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
231 KB
Volume
28
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Allylsilanes in organic synthesis; stere
Allylsilanes in organic synthesis; stereoselective reaction of chiral ester-allylsilanes with m-CPBA
โœ Andrew T. Russell; Garry Procter ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 229 KB

The ester-allylsilanes ( 5) and ( 6) and the acid-allylsilane (7) react stereoselectively with m-CPBA; the major product from ( 5) and ( 7) was the y-lactone (4), whereas (6) failed to undergo lactonisation, the major product in this case was the P,wpoxy-silane (12).