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Addition of a cyclopropyl alkyne to tetramesityldigermene: evidence for a biradical intermediate

โœ Scribed by Hurni, Krysten L.; Baines, Kim M.

Book ID
121372843
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
640 KB
Volume
47
Category
Article
ISSN
1359-7345

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ChemInform Abstract: Cycloaddition React
ChemInform Abstract: Cycloaddition Reactions of Aldehydes to Tetramesityldisilene and Tetramesitylgermasilene: Evidence for a Biradical Intermediate.
โœ Craig E. Dixon; Donald W. Hughes; Kim M. Baines ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

The formation of products (IV)/(V) and (VIII)/(IX) in the title reactions is explained by either disproportionation or ring closure of an intermediate biradical derived from initial bond formation between the oxygen atom of the aldehyde and the doubly bonded silicon atom of the dimetallene. -(DIXON,