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Addition of Cyclopropyl Alkynes to a Brook Silene: Definitive Evidence for a Biradical Intermediate

โœ Scribed by Milnes, Kaarina K.; Jennings, Michael C.; Baines, Kim M.


Book ID
126768886
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
188 KB
Volume
128
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Cycloaddition React
โœ Craig E. Dixon; Donald W. Hughes; Kim M. Baines ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

The formation of products (IV)/(V) and (VIII)/(IX) in the title reactions is explained by either disproportionation or ring closure of an intermediate biradical derived from initial bond formation between the oxygen atom of the aldehyde and the doubly bonded silicon atom of the dimetallene. -(DIXON,