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Cycloaddition Reactions of Aldehydes to Tetramesityldisilene and Tetramesitylgermasilene: Evidence for a Biradical Intermediate

โœ Scribed by Dixon, Craig E.; Hughes, Donald W.; Baines, Kim M.


Book ID
126057930
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
90 KB
Volume
120
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Cycloaddition React
โœ Craig E. Dixon; Donald W. Hughes; Kim M. Baines ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

The formation of products (IV)/(V) and (VIII)/(IX) in the title reactions is explained by either disproportionation or ring closure of an intermediate biradical derived from initial bond formation between the oxygen atom of the aldehyde and the doubly bonded silicon atom of the dimetallene. -(DIXON,