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ChemInform Abstract: Cycloaddition Reactions of Aldehydes to Tetramesityldisilene and Tetramesitylgermasilene: Evidence for a Biradical Intermediate.

✍ Scribed by Craig E. Dixon; Donald W. Hughes; Kim M. Baines

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199915191

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✦ Synopsis

The formation of products (IV)/(V) and (VIII)/(IX) in the title reactions is explained by either disproportionation or ring closure of an intermediate biradical derived from initial bond formation between the oxygen atom of the aldehyde and the doubly bonded silicon atom of the dimetallene. -(DIXON,

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