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Addition compounds of alkali metal hydrides. 13. Reactions of alkali metal hydrides with trialkylboranes. Synthesis and dissociation of alkali metal trialkylborohydrides. Ethyl ether-organoborane as a reversible "solvent" for lithium hydride

✍ Scribed by Brown, Herbert C.; Khuri, Albert.; Kim, S. C.


Book ID
121853610
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
733 KB
Volume
16
Category
Article
ISSN
0020-1669

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Addition compounds of alkali metal hydri
✍ Herbert C. Brown; John L. Hubbard; Bakthan Singaram πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 403 KB

Abdrad-Trialkylborancs react rapidly with lithium aluminium hydride (LAH) in dicthyl ether in the presence of triethykncdiamim (TED) at 0" to form the corresponding lithium triakylborohydrides and aluminum hydride. The aluminum hydride precipitates out of solution as its triethylenediamine adduct. T