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Addition compounds of alkali metal hydrides. 30. Rapid reaction of trialkylboranes with lithium aluminum hydride. A novel and quantitative synthesis of lithium dialkylborohydrides

✍ Scribed by Brown, Herbert C.; Rangaishenvi, Milind V.; Racherla, Uday S.


Book ID
127236678
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
375 KB
Volume
52
Category
Article
ISSN
0022-3263

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Addition compounds of alkali metal hydri
✍ Herbert C. Brown; John L. Hubbard; Bakthan Singaram πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 403 KB

Abdrad-Trialkylborancs react rapidly with lithium aluminium hydride (LAH) in dicthyl ether in the presence of triethykncdiamim (TED) at 0" to form the corresponding lithium triakylborohydrides and aluminum hydride. The aluminum hydride precipitates out of solution as its triethylenediamine adduct. T