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Addition compounds of alkali metal hydrides. 14. The reaction of trialkylboranes with lithium trialkylborohydrides

✍ Scribed by Brown, Herbert C.; Khuri, Albert; Krishnamurthy, S.


Book ID
126131145
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
624 KB
Volume
99
Category
Article
ISSN
0002-7863

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Addition compounds of alkali metal hydri
✍ Herbert C. Brown; John L. Hubbard; Bakthan Singaram πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 403 KB

Abdrad-Trialkylborancs react rapidly with lithium aluminium hydride (LAH) in dicthyl ether in the presence of triethykncdiamim (TED) at 0" to form the corresponding lithium triakylborohydrides and aluminum hydride. The aluminum hydride precipitates out of solution as its triethylenediamine adduct. T