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Addition compounds of alkali metal hydrides. 15. Steric effects in the reaction of representative trialkylboranes with lithium and sodium hydrides to form the corresponding trialkylborohydrides

✍ Scribed by Brown, Herbert C.; Krishnamurthy, S.; Hubbard, John L.

Book ID: 118275371
Publisher: American Chemical Society
Year: 1978
Tongue: English
Weight: 807 KB
Volume: 100
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00479a016

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Abdrad-Trialkylborancs react rapidly with lithium aluminium hydride (LAH) in dicthyl ether in the presence of triethykncdiamim (TED) at 0" to form the corresponding lithium triakylborohydrides and aluminum hydride. The aluminum hydride precipitates out of solution as its triethylenediamine adduct. T