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Acid—base titrations in aqueous micellar systems

✍ Scribed by A.L. Underwood

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
481 KB
Volume
93
Category
Article
ISSN
0003-2670

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✦ Synopsis

Some water-insoluble carborylic acids and amines have been titrated in aqueous surfactant solutions to demonstrate that solubilization in micelles provides a useful solvent system for certain acid-base titrations. Potentiometric titrations can be very slow because of electrode drift in these solutions, but visual titrations are convenient. Observed ph-shifts are generally interpretable in terms of the influence of micellar charge on the work of proton removal.

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