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Resolution of acid strength in non-aqueous acid-base titrations

✍ Scribed by A.Gustavo González; M.Angeles Herrador; Agustín G. Asuero

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
391 KB
Volume
281
Category
Article
ISSN
0003-2670

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✦ Synopsis

The equivalence between the resolution of the acid strength in a given solvent and the ratio (p*/p) of Hammett's reaction constants for the solvent and water was obtained on the basis of empirical linear free energy relationships (LFER). The resolution for benzoic acids in a number of solvents from reported data was calculated by regression techniques. Fair correlations between the resolution and some solvent parameters such as the Mayer-Gutman acceptor number and the normalized Diiroth polarity parameter were observed.

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