Some water-insoluble carborylic acids and amines have been titrated in aqueous surfactant solutions to demonstrate that solubilization in micelles provides a useful solvent system for certain acid-base titrations. Potentiometric titrations can be very slow because of electrode drift in these solutio
Acid-base titrations of substituted benzoic acids in micellar systems
β Scribed by Ezio Pelizzetti; Edmondo Pramauro
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 267 KB
- Volume
- 117
- Category
- Article
- ISSN
- 0003-2670
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β¦ Synopsis
The dissociation equilibria of substituted benzoic acids in cationic and anionic micellar systems, investigated potentiometrically. show pK shifts of less than 1.0 in cationic and 0.5-3 in anionic micelles. Visual titrations of otherwise insoluble acids in cntionic micelles give satisfactory results.
π SIMILAR VOLUMES
The equivalence between the resolution of the acid strength in a given solvent and the ratio (p\*/p) of Hammett's reaction constants for the solvent and water was obtained on the basis of empirical linear free energy relationships (LFER). The resolution for benzoic acids in a number of solvents from