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Automatic titrations in unsegmented flow systems based on variable flow-rate patterns: Part 1. Principles and applications to acid-base titrations

✍ Scribed by J. Marcos; A. íos; M. Valcárcel


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
485 KB
Volume
261
Category
Article
ISSN
0003-2670

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✦ Synopsis


Automatx acid-base trtratlons were carned out by generating pH grachents m a continuous-flow mamfold A programmable, computer-controlled pump was used to produce vanable, reproducible flow-rate patterns that were used to mcrease gradually the tltrant concentration m the flow system A colorlmetrlc mdlcator reagent allowed the spectrophotmetrx detectIon of the eqmvalence pomt Strong and weak acids, both alone and m mtiures, and two protons of the same acid were titrated wth a relative standard deviation of 18% The procedure was apphed to the analysis of various real samples