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Acid-catalyzed thermolysis of dicyclopropyl ketimines. Substituent effects on the course of the rearrangement

✍ Scribed by Harry H. Wasserman; Robert P. Dion

Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
183 KB
Volume
24
Category
Article
ISSN
0040-4039

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## Abstract The acid catalyzed rearrangement of 1‐bromotetracyclo[4.3.0.0^2.5^0^3.8^]nonan‐4‐one 1b has been studied. With aqueous HBr, the exclusive formation of 2,7‐dibromotricyclo[4.2.1.0^3.7^]‐nonan‐4‐one **4b** was observed. This structure was established by X‐ray analysis. The divergency in b