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The cope rearrangement: substituent effects on equilibria of bridged homotropilidenes

โœ Scribed by Grant R. Krow; Kermit C. Ramey

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
191 KB
Volume
12
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

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The activation parameters [โˆ†G (200 K), โˆ†H , and โˆ†S ] for compounds, together with those for related compounds previously reported in the literature, show that conjugating the degenerate Cope rearrangements of barbaralane (1a) and several semibullvalenes (3a, 7a, 8a), and for those of a subsituents (

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Recent studies have shown that the monohqto indenyl compounds (I) of a number of main group and transition series metals exhibit dynanic intramolecular (fluxional) rearrangements.' In the case of the indenylsilanes (Ia) a kinetically slower hydrogen migration occurs, giving rise to non-fluxional pos